The print version of Library of Congress Subject Headings (LCSH; five thick red volumes) is what many catalogers have used for a long time. Some catalogers have begun using "Library of Congress Authorities," which is freely searchable online.
But just today, a participant at a session I attended shared that the entire LCSH has recently been uploaded at lcsh.info, which is an experimental service that aims to "encourage experimentation and use of LCSH on the web."
It's far from being an ebook that non-techies like me can use easily, but if you understand what Simple Knowledge Organization System (SKOS) is all about, you might be able to make it work for you and develop new ways of using LCSH online in non-traditional ways, aside from not having to buy a new set every few years.
See some of the possibilities at "Semantic Search the US Library of Congress." If you know what an API is, you should check out the summary.
SLA 2008: LCSH for Free
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